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  4. A Low-Temperature-Resistant Flexible Organic Crystal with Circularly Polarized Luminescence
 
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A Low-Temperature-Resistant Flexible Organic Crystal with Circularly Polarized Luminescence

Journal
Angewandte Chemie International Edition
ISSN
1433-7851
Date Issued
2022
Author(s)
Li, Liang 
Physics, Mathematics, Computer science 
Pan, Xiuhong
Zheng, Anyi
Di, Qi
Duan, Pengfei
Ye, Kaiqi
Naumov, Panče
Zhang, Hongyu
Yu, Xu
DOI
10.1002/anie.202203938
URI
https://depot.sorbonne.ae/handle/20.500.12458/1274
Abstract
Flexible organic crystals with unique mechanical properties and excellent optical properties are of paramount significance for their wide applications in various research fields such as adaptive optics and soft robotics. However, low-temperature-resistant flexible organic crystal with circularly polarized luminescence (CPL) ability has never been reported. Herein, chiral organic crystals with CPL activity and low-temperature flexibility (77 K) are fabricated by the solvent diffusion method from chiral Schiff bases, S(R)-4- b romo-2-(((1- p henyl e thyl)imino) m ethyl) p henol (S(R)-BPEMP). The corresponding chiroptical properties for the two enantiomeric crystals were thoroughly investigated, including the measurements of circular dichroism (CD) and CPL. To the best of our knowledge, this is the first report on low-molecular-weight flexible organic crystals with CPL activity, and we believe that the results will give a new impetus to the research of organic crystals.
Subjects
  • circularly polarized ...

  • flexible crystals

  • low-temperature resis...

  • optical waveguides

File(s)
 A Low‐Temperature‐Resistant Flexible Organic Crystal with Circularly Polarized.pdf (2.13 MB)
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Acquisition Date
Oct 25, 2022
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